In case anyone's interested the website http://www.neo-folk.it/
has 6 complete compilation albums that can be downloaded for free. Pretty obscure stuff. No major names in the movement but worth a listen. I haven't got through them yet so I haven't any recommendations. It also has links to downloadable MP3s of some better known bands like Death in June, Kirilian Camera and Fin de Siecle. There's even a track by that well known Israeli folk metal artist Brigitte Bardot